Crystal structure magnetic properties and hyperfine interactions in RFe4Al8 (R = rare earth) systems

I. Felner*, I. Nowik

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

109 Scopus citations

Abstract

X-ray, magnetic susceptibility and 57Fe, 151Eu, 155Gd and 170Yb Mössbauer studies were performed. Detailed analysis of X-ray intensities yields all ion locations and interatomic distances in the body centered tetragonal structure (space group I4/MMM). The unit cell contains two formula units. The rare earth, iron and aluminum occupy the 2(a), 8(f) and 8(i) and 8(j) crystallographic sites, respectively. The susceptibility and Mössbauer studies indicate the existence of two independent magnetic sublattices. The iron sublattice orders into an antiferromagnetic structure at about 120 K, whereas the rare earth sublattice orders (excluding those with La, Ce, Eu, Y and Lu) antiferromagnetically at about 20 K. The 57Fe, 151Eu, 155Gd and 170Yb Mössbauer studies yield, in addition to the hyperfine interaction parameters, also the direction along which the moments are aligned. In EuFe4Al8 the Eu ion is in a mixed valent state.

Original languageEnglish
Pages (from-to)951-956
Number of pages6
JournalJournal of Physics and Chemistry of Solids
Volume39
Issue number9
DOIs
StatePublished - 1978

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