Crystal Structure of Tetraammine Zinc(II) Peroxodisulfate and Barium Peroxodisulfate Tetrahydrate

A. G. Medvedev; T. A. Tripol’skaya; E. A. Mel’nik; P. A. Egorov; N. S. Mayorov; A. A. Mikhaylov; O. Lev; P. V. Prikhodchenko

doi:10.1134/S1070328423601553

Crystal Structure of Tetraammine Zinc(II) Peroxodisulfate and Barium Peroxodisulfate Tetrahydrate

A. G. Medvedev, T. A. Tripol’skaya, E. A. Mel’nik, P. A. Egorov, N. S. Mayorov, A. A. Mikhaylov, O. Lev^*, P. V. Prikhodchenko^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Abstract: Zinc(II) tetraammine peroxodisulfate [Zn(NH₃)₄]S₂O₈ (I) and barium peroxodisulfate tetrahydrate BaS₂O₈·4H₂O (II) were synthesized by interaction of an aqueous solution of ammonium peroxodisulfate with a zinc peroxide and barium hydroxide, respectively. The crystal structures (CIF file CCDC nos. 2311248 (I) and 2311249 (II)) were determined by single crystal X-ray diffraction. The crystal structure of I, for which X-ray powder diffraction structural data were previously reported, has been redetermined and clarified. The crystal packing of I consists of hydrogen-bonded chains parallel to the b-axis connected in a three-dimensional structure with H-bonds between adjacent chains. The compound II is coordination polymer with coordination number of barium cation equal to 9. The crystal packing of II consists of channels in which water molecules are held by H-bonds. Compounds I and II were characterized by DTA and TGA revealing thermal stability up to 170 and 90°C.

Original language	English
Pages (from-to)	374-383
Number of pages	10
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	50
Issue number	6
DOIs	https://doi.org/10.1134/S1070328423601553
State	Published - Jun 2024

Bibliographical note

Publisher Copyright:
© Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 6, pp. 374–383. Pleiades Publishing, Ltd., 2024.

Keywords

X-ray diffraction
crystal packing
hydrogen bonds
peroxodisulfates

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10.1134/S1070328423601553

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Medvedev, A. G., Tripol’skaya, T. A., Mel’nik, E. A., Egorov, P. A., Mayorov, N. S., Mikhaylov, A. A., Lev, O., & Prikhodchenko, P. V. (2024). Crystal Structure of Tetraammine Zinc(II) Peroxodisulfate and Barium Peroxodisulfate Tetrahydrate. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 50(6), 374-383. https://doi.org/10.1134/S1070328423601553

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abstract = "Abstract: Zinc(II) tetraammine peroxodisulfate [Zn(NH3)4]S2O8 (I) and barium peroxodisulfate tetrahydrate BaS2O8·4H2O (II) were synthesized by interaction of an aqueous solution of ammonium peroxodisulfate with a zinc peroxide and barium hydroxide, respectively. The crystal structures (CIF file CCDC nos. 2311248 (I) and 2311249 (II)) were determined by single crystal X-ray diffraction. The crystal structure of I, for which X-ray powder diffraction structural data were previously reported, has been redetermined and clarified. The crystal packing of I consists of hydrogen-bonded chains parallel to the b-axis connected in a three-dimensional structure with H-bonds between adjacent chains. The compound II is coordination polymer with coordination number of barium cation equal to 9. The crystal packing of II consists of channels in which water molecules are held by H-bonds. Compounds I and II were characterized by DTA and TGA revealing thermal stability up to 170 and 90°C.",

keywords = "X-ray diffraction, crystal packing, hydrogen bonds, peroxodisulfates",

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note = "Publisher Copyright: {\textcopyright} Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 6, pp. 374–383. Pleiades Publishing, Ltd., 2024.",

year = "2024",

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doi = "10.1134/S1070328423601553",

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T1 - Crystal Structure of Tetraammine Zinc(II) Peroxodisulfate and Barium Peroxodisulfate Tetrahydrate

AU - Medvedev, A. G.

AU - Tripol’skaya, T. A.

AU - Mel’nik, E. A.

AU - Egorov, P. A.

AU - Mayorov, N. S.

AU - Mikhaylov, A. A.

AU - Lev, O.

AU - Prikhodchenko, P. V.

N1 - Publisher Copyright: © Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 6, pp. 374–383. Pleiades Publishing, Ltd., 2024.

PY - 2024/6

Y1 - 2024/6

N2 - Abstract: Zinc(II) tetraammine peroxodisulfate [Zn(NH3)4]S2O8 (I) and barium peroxodisulfate tetrahydrate BaS2O8·4H2O (II) were synthesized by interaction of an aqueous solution of ammonium peroxodisulfate with a zinc peroxide and barium hydroxide, respectively. The crystal structures (CIF file CCDC nos. 2311248 (I) and 2311249 (II)) were determined by single crystal X-ray diffraction. The crystal structure of I, for which X-ray powder diffraction structural data were previously reported, has been redetermined and clarified. The crystal packing of I consists of hydrogen-bonded chains parallel to the b-axis connected in a three-dimensional structure with H-bonds between adjacent chains. The compound II is coordination polymer with coordination number of barium cation equal to 9. The crystal packing of II consists of channels in which water molecules are held by H-bonds. Compounds I and II were characterized by DTA and TGA revealing thermal stability up to 170 and 90°C.

AB - Abstract: Zinc(II) tetraammine peroxodisulfate [Zn(NH3)4]S2O8 (I) and barium peroxodisulfate tetrahydrate BaS2O8·4H2O (II) were synthesized by interaction of an aqueous solution of ammonium peroxodisulfate with a zinc peroxide and barium hydroxide, respectively. The crystal structures (CIF file CCDC nos. 2311248 (I) and 2311249 (II)) were determined by single crystal X-ray diffraction. The crystal structure of I, for which X-ray powder diffraction structural data were previously reported, has been redetermined and clarified. The crystal packing of I consists of hydrogen-bonded chains parallel to the b-axis connected in a three-dimensional structure with H-bonds between adjacent chains. The compound II is coordination polymer with coordination number of barium cation equal to 9. The crystal packing of II consists of channels in which water molecules are held by H-bonds. Compounds I and II were characterized by DTA and TGA revealing thermal stability up to 170 and 90°C.

KW - X-ray diffraction

KW - crystal packing

KW - hydrogen bonds

KW - peroxodisulfates

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Crystal Structure of Tetraammine Zinc(II) Peroxodisulfate and Barium Peroxodisulfate Tetrahydrate

Abstract

Bibliographical note

Keywords

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