Cyclometalated phosphine-based Ir(III) pincer complex as a catalyst for Oppenauer-type oxidation of alcohols

Roy Levy; Clarite Azerraf; Dmitri Gelman; Karola Rueck-Braun; Pramesh N. Kapoor

doi:10.1016/j.catcom.2009.10.018

Cyclometalated phosphine-based Ir(III) pincer complex as a catalyst for Oppenauer-type oxidation of alcohols

Roy Levy, Clarite Azerraf, Dmitri Gelman^*, Karola Rueck-Braun, Pramesh N. Kapoor

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Transfer dehydrogenation of ketones was efficiently carried out in acetone under air by means of a new Ir(III)-cyclometalated pincer type catalyst bearing a robust triptycene-based ligand.

Original language	English
Pages (from-to)	298-301
Number of pages	4
Journal	Catalysis Communications
Volume	11
Issue number	4
DOIs	https://doi.org/10.1016/j.catcom.2009.10.018
State	Published - 15 Dec 2009

Keywords

Iridium
Oppenauer oxidation
Pincer complexes
Transfer dehydrogenation

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10.1016/j.catcom.2009.10.018

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title = "Cyclometalated phosphine-based Ir(III) pincer complex as a catalyst for Oppenauer-type oxidation of alcohols",

abstract = "Transfer dehydrogenation of ketones was efficiently carried out in acetone under air by means of a new Ir(III)-cyclometalated pincer type catalyst bearing a robust triptycene-based ligand.",

keywords = "Iridium, Oppenauer oxidation, Pincer complexes, Transfer dehydrogenation",

author = "Roy Levy and Clarite Azerraf and Dmitri Gelman and Karola Rueck-Braun and Kapoor, {Pramesh N.}",

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T1 - Cyclometalated phosphine-based Ir(III) pincer complex as a catalyst for Oppenauer-type oxidation of alcohols

AU - Levy, Roy

AU - Azerraf, Clarite

AU - Gelman, Dmitri

AU - Rueck-Braun, Karola

AU - Kapoor, Pramesh N.

PY - 2009/12/15

Y1 - 2009/12/15

N2 - Transfer dehydrogenation of ketones was efficiently carried out in acetone under air by means of a new Ir(III)-cyclometalated pincer type catalyst bearing a robust triptycene-based ligand.

AB - Transfer dehydrogenation of ketones was efficiently carried out in acetone under air by means of a new Ir(III)-cyclometalated pincer type catalyst bearing a robust triptycene-based ligand.

KW - Iridium

KW - Oppenauer oxidation

KW - Pincer complexes

KW - Transfer dehydrogenation

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AN - SCOPUS:71549157412

SN - 1566-7367

VL - 11

SP - 298

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JO - Catalysis Communications

JF - Catalysis Communications

IS - 4

ER -

Cyclometalated phosphine-based Ir(III) pincer complex as a catalyst for Oppenauer-type oxidation of alcohols

Abstract

Keywords

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