Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst

Kobi Oded; Sanaa Musa; Dmitri Gelman; Jochanan Blum

doi:10.1016/j.catcom.2012.01.017

Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst

Kobi Oded, Sanaa Musa, Dmitri Gelman^*, Jochanan Blum

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.

Original language	American English
Pages (from-to)	68-70
Number of pages	3
Journal	Catalysis Communications
Volume	20
DOIs	https://doi.org/10.1016/j.catcom.2012.01.017
State	Published - 5 Apr 2012

Bibliographical note

Funding Information:
This research was supported by the Israel Science Foundation Grants No. 13/11 (DG) and 229/10 (JB).

Keywords

Acceptorless dehydrogenation
Iridium
Sol-gel processes
sp -Metalated pincer complex

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10.1016/j.catcom.2012.01.017

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title = "Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst",

abstract = "We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.",

keywords = "Acceptorless dehydrogenation, Iridium, Sol-gel processes, sp -Metalated pincer complex",

author = "Kobi Oded and Sanaa Musa and Dmitri Gelman and Jochanan Blum",

note = "Funding Information: This research was supported by the Israel Science Foundation Grants No. 13/11 (DG) and 229/10 (JB). ",

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T1 - Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst

AU - Oded, Kobi

AU - Musa, Sanaa

AU - Gelman, Dmitri

AU - Blum, Jochanan

N1 - Funding Information: This research was supported by the Israel Science Foundation Grants No. 13/11 (DG) and 229/10 (JB).

PY - 2012/4/5

Y1 - 2012/4/5

N2 - We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.

AB - We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.

KW - Acceptorless dehydrogenation

KW - Iridium

KW - Sol-gel processes

KW - sp -Metalated pincer complex

UR - http://www.scopus.com/inward/record.url?scp=84856482884&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2012.01.017

DO - 10.1016/j.catcom.2012.01.017

M3 - Article

AN - SCOPUS:84856482884

SN - 1566-7367

VL - 20

SP - 68

EP - 70

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst

Abstract

Bibliographical note

Keywords

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