TY - JOUR
T1 - Dehydrogenation of alcohols under ambient atmosphere by a recyclable sol-gel encaged iridium pincer catalyst
AU - Oded, Kobi
AU - Musa, Sanaa
AU - Gelman, Dmitri
AU - Blum, Jochanan
N1 - Funding Information:
This research was supported by the Israel Science Foundation Grants No. 13/11 (DG) and 229/10 (JB).
PY - 2012/4/5
Y1 - 2012/4/5
N2 - We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.
AB - We demonstrate that a sol-gel entrapped iridium-pincer catalyst 1 is capable of promoting acceptorless dehydrogenation of primary and secondary alcohols. Although the dehydrogenations by the non-heterogenized catalyst are faster than by the sol-gel encaged complex, recyclability and significant stabilization of the organometallic species toward non-inert conditions represent a clear advantage from the environmental and practical points of view.
KW - Acceptorless dehydrogenation
KW - Iridium
KW - Sol-gel processes
KW - sp -Metalated pincer complex
UR - http://www.scopus.com/inward/record.url?scp=84856482884&partnerID=8YFLogxK
U2 - 10.1016/j.catcom.2012.01.017
DO - 10.1016/j.catcom.2012.01.017
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AN - SCOPUS:84856482884
SN - 1566-7367
VL - 20
SP - 68
EP - 70
JO - Catalysis Communications
JF - Catalysis Communications
ER -