Dehydrogenative cross-coupling of primary and secondary alcohols

Sanaa Musa; Lutz Ackermann; Dmitri Gelman

doi:10.1002/adsc.201300656

Dehydrogenative cross-coupling of primary and secondary alcohols

Sanaa Musa, Lutz Ackermann, Dmitri Gelman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

91 Scopus citations

Abstract

Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.

Original language	English
Pages (from-to)	3077-3080
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	355
Issue number	14-15
DOIs	https://doi.org/10.1002/adsc.201300656
State	Published - 11 Oct 2013

Keywords

Acceptorless dehydrogenation
Crosscoupling
Innocent ligands
Ligand-metal cooperation
Pincer ligands

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keywords = "Acceptorless dehydrogenation, Crosscoupling, Innocent ligands, Ligand-metal cooperation, Pincer ligands",

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AU - Ackermann, Lutz

AU - Gelman, Dmitri

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N2 - Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.

AB - Homo-and cross-coupling of alcohols resulting in the formation of the corresponding ketones in very good to excellent yield was realized through the one-pot sequence of dehydrogenation/ aldol condensation/hydrogenation accompanied by the release of molecular hydrogen. The dehydrogenation and hydrogenation steps are catalyzed by the previously reported ruthernium-and iridiumbased ligand-metal cooperating catalysts.

KW - Acceptorless dehydrogenation

KW - Crosscoupling

KW - Innocent ligands

KW - Ligand-metal cooperation

KW - Pincer ligands

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ER -

Dehydrogenative cross-coupling of primary and secondary alcohols

Abstract

Keywords

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