Desulfurization of hydrocarbons by electron transfer oxidative polymerization of heteroaromatic sulfides catalyzed by H5PV 2Mo10O40 polyoxometalate

Alexander M. Khenkin; Ronny Neumann

doi:10.1002/cssc.201000402

Desulfurization of hydrocarbons by electron transfer oxidative polymerization of heteroaromatic sulfides catalyzed by H₅PV ₂Mo₁₀O₄₀ polyoxometalate

Alexander M. Khenkin, Ronny Neumann^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Gone in 7200 Seconds: Heteroaromatic thiophene derivatives, refractory to hydrodesulfurization, are removed from hydrocarbons by oxidative polymerization over H₅PV₂Mo₁₀O₄₀/SiO₂ as a recyclable, heterogeneous catalyst. The levels of sulfur-containing compounds reach sub-ppm to nondetectable levels, as analyzed by gas chromatography with a flame photometric detector.

Original language	English
Pages (from-to)	346-348
Number of pages	3
Journal	ChemSusChem
Volume	4
Issue number	3
DOIs	https://doi.org/10.1002/cssc.201000402
State	Published - 21 Mar 2011
Externally published	Yes

Keywords

Desulfurization
Heterogeneous catalysis
Oxidation-polyoxometalates
Sulfides

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10.1002/cssc.201000402

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N2 - Gone in 7200 Seconds: Heteroaromatic thiophene derivatives, refractory to hydrodesulfurization, are removed from hydrocarbons by oxidative polymerization over H5PV2Mo10O40/SiO2 as a recyclable, heterogeneous catalyst. The levels of sulfur-containing compounds reach sub-ppm to nondetectable levels, as analyzed by gas chromatography with a flame photometric detector.

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KW - Desulfurization

KW - Heterogeneous catalysis

KW - Oxidation-polyoxometalates

KW - Sulfides

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Desulfurization of hydrocarbons by electron transfer oxidative polymerization of heteroaromatic sulfides catalyzed by H₅PV ₂Mo₁₀O₄₀ polyoxometalate

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