Determination of kinetic acidities through an electrogenerated base. Application to the case of a family of NH acids

F. Maran; A. Goldblum; F. D'Angeli; E. Vianello

doi:10.1016/0013-4686(88)80007-0

Determination of kinetic acidities through an electrogenerated base. Application to the case of a family of NH acids

F. Maran^*, A. Goldblum, F. D'Angeli, E. Vianello

^*Corresponding author for this work

School of Pharmacy

Research output: Contribution to journal › Article › peer-review

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Abstract

An electrochemical method is utilized for the determination of kinetic acidities of weak acids. The electrogeneration of the dianion of tetraphenylethylene in MeCN and its protonation by weak acids can be easily and quantitatively monitored through cyclic voltammetry. The method is applied to a family of NH acids N-substituted isobutyramides) and some correlations are presented.

Original language	English
Pages (from-to)	227-229
Number of pages	3
Journal	Electrochimica Acta
Volume	33
Issue number	2
DOIs	https://doi.org/10.1016/0013-4686(88)80007-0
State	Published - Feb 1988

Bibliographical note

Funding Information:
Acknowledgement~The National Research Council, the Ministry of Education, and the National Council for Research and Development are gratefully acknowledged for financial support.

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abstract = "An electrochemical method is utilized for the determination of kinetic acidities of weak acids. The electrogeneration of the dianion of tetraphenylethylene in MeCN and its protonation by weak acids can be easily and quantitatively monitored through cyclic voltammetry. The method is applied to a family of NH acids N-substituted isobutyramides) and some correlations are presented.",

author = "F. Maran and A. Goldblum and F. D'Angeli and E. Vianello",

note = "Funding Information: Acknowledgement~The National Research Council, the Ministry of Education, and the National Council for Research and Development are gratefully acknowledged for financial support.",

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AU - Goldblum, A.

AU - D'Angeli, F.

AU - Vianello, E.

N1 - Funding Information: Acknowledgement~The National Research Council, the Ministry of Education, and the National Council for Research and Development are gratefully acknowledged for financial support.

PY - 1988/2

Y1 - 1988/2

N2 - An electrochemical method is utilized for the determination of kinetic acidities of weak acids. The electrogeneration of the dianion of tetraphenylethylene in MeCN and its protonation by weak acids can be easily and quantitatively monitored through cyclic voltammetry. The method is applied to a family of NH acids N-substituted isobutyramides) and some correlations are presented.

AB - An electrochemical method is utilized for the determination of kinetic acidities of weak acids. The electrogeneration of the dianion of tetraphenylethylene in MeCN and its protonation by weak acids can be easily and quantitatively monitored through cyclic voltammetry. The method is applied to a family of NH acids N-substituted isobutyramides) and some correlations are presented.

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Determination of kinetic acidities through an electrogenerated base. Application to the case of a family of NH acids

Abstract

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