Diabatic transition state theory and the concept of temperature

G. Ludwig Hofacker; R. D. Levine

doi:10.1016/0009-2614(72)80142-8

Diabatic transition state theory and the concept of temperature

G. Ludwig Hofacker^*
, R. D. Levine

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

A modified transition state theory, appropriate for direct reactions, which incorporates dynamic constraints and can account for population inversion, is presented. It is shown that the distribution of vibrational states can be characterized by a lagrangian parameter that can be interpreted as temperature.

Original language	English
Pages (from-to)	165-170
Number of pages	6
Journal	Chemical Physics Letters
Volume	15
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(72)80142-8
State	Published - 1 Aug 1972

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abstract = "A modified transition state theory, appropriate for direct reactions, which incorporates dynamic constraints and can account for population inversion, is presented. It is shown that the distribution of vibrational states can be characterized by a lagrangian parameter that can be interpreted as temperature.",

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Diabatic transition state theory and the concept of temperature

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