TY - JOUR
T1 - Didecyldimethylammonium bromide (DDAB)
T2 - a universal, robust, and highly potent phase-transfer catalyst for diverse organic transformations
AU - Chidambaram, Mandan
AU - Sonavane, Sachin U.
AU - de la Zerda, Jaima
AU - Sasson, Yoel
PY - 2007/8/6
Y1 - 2007/8/6
N2 - Didecyldimethylammonium bromide (DDAB) has been scrutinized in comparison with traditional phase-transfer catalysts in variety of liquid-liquid reactions. It was found to be an exceptionally comprehensive, durable, and highly efficient phase-transfer catalyst (PTC) in a number of representative organic transformations such as C- and N-alkylations, isomerization, esterification, elimination, cyanation, bromination, and oxidation under very mild conditions of temperature and mixing. It was confirmed that DDAB is an exceedingly accessible and concurrently a highly liphophilic phase-transfer catalyst. This unprecedented characteristic renders DDAB to be a multipurpose catalyst that functions effectively both in mass transfer controlled and chemically controlled phase-transfer reactions.
AB - Didecyldimethylammonium bromide (DDAB) has been scrutinized in comparison with traditional phase-transfer catalysts in variety of liquid-liquid reactions. It was found to be an exceptionally comprehensive, durable, and highly efficient phase-transfer catalyst (PTC) in a number of representative organic transformations such as C- and N-alkylations, isomerization, esterification, elimination, cyanation, bromination, and oxidation under very mild conditions of temperature and mixing. It was confirmed that DDAB is an exceedingly accessible and concurrently a highly liphophilic phase-transfer catalyst. This unprecedented characteristic renders DDAB to be a multipurpose catalyst that functions effectively both in mass transfer controlled and chemically controlled phase-transfer reactions.
KW - Catalytic applications
KW - DDAB
KW - Didecyldimethylammonium bromide
KW - Organic transformations
KW - Phase-transfer catalysts
UR - http://www.scopus.com/inward/record.url?scp=34250731682&partnerID=8YFLogxK
U2 - 10.1016/j.tet.2007.05.017
DO - 10.1016/j.tet.2007.05.017
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AN - SCOPUS:34250731682
SN - 0040-4020
VL - 63
SP - 7696
EP - 7701
JO - Tetrahedron
JF - Tetrahedron
IS - 32
ER -