TY - JOUR
T1 - Direct visualization of the H-Xe bond in xenon hydrides
T2 - Xenon isotopic shift in the IR spectra
AU - Feldman, Vladimir I.
AU - Kobzarenko, Alexey V.
AU - Baranova, Irina A.
AU - Danchenko, Alexander V.
AU - Sukhov, Fedor F.
AU - Tsivion, Ehud
AU - Gerber, R. Benny
PY - 2009
Y1 - 2009
N2 - IR spectra of xenon hydrides (HXeCCH, HXeCC, and HXeH) obtained from different xenon isotopes (129Xe and 13Xe) exhibit a small but detectable and reproducible isotopic shift in the absorptions assigned to H-Xe stretching (by 0.17-0.38 cm-1). To our knowledge, it is the first direct experimental evidence for the H-Xe bond in HXeY type compounds. The shift magnitude is in good agreement with quantum-chemical calculations.
AB - IR spectra of xenon hydrides (HXeCCH, HXeCC, and HXeH) obtained from different xenon isotopes (129Xe and 13Xe) exhibit a small but detectable and reproducible isotopic shift in the absorptions assigned to H-Xe stretching (by 0.17-0.38 cm-1). To our knowledge, it is the first direct experimental evidence for the H-Xe bond in HXeY type compounds. The shift magnitude is in good agreement with quantum-chemical calculations.
UR - http://www.scopus.com/inward/record.url?scp=70449433256&partnerID=8YFLogxK
U2 - 10.1063/1.3250426
DO - 10.1063/1.3250426
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AN - SCOPUS:70449433256
SN - 0021-9606
VL - 131
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 15
M1 - 151101
ER -