Disequilibrating azobenzenes by visible-light sensitization under confinement

Julius Gemen, Jonathan R. Church, Tero Petri Ruoko, Nikita Durandin, Michał J. Białek, Maren Weißenfels, Moran Feller, Miri Kazes, Magdalena Odaybat, Veniamin A. Borin, Rishir Kalepu, Yael Diskin-Posner, Dan Oron, Matthew J. Fuchter, Arri Priimagi, Igor Schapiro*, Rafal Klajn*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

Photoisomerization of azobenzenes from their stable E isomer to the metastable Z state is the basis of numerous applications of these molecules. However, this reaction typically requires ultraviolet light, which limits applicability. In this study, we introduce disequilibration by sensitization under confinement (DESC), a supramolecular approach to induce the E-to-Z isomerization by using light of a desired color, including red. DESC relies on a combination of a macrocyclic host and a photosensitizer, which act together to selectively bind and sensitize E-azobenzenes for isomerization. The Z isomer lacks strong affinity for and is expelled from the host, which can then convert additional E-azobenzenes to the Z state. In this way, the host–photosensitizer complex converts photon energy into chemical energy in the form of out-of-equilibrium photostationary states, including ones that cannot be accessed through direct photoexcitation.

Original languageAmerican English
Article numberadh9059
JournalScience
Volume381
Issue number6664
DOIs
StatePublished - 22 Sep 2023

Bibliographical note

Publisher Copyright:
Copyright © 2023 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

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