Dual asymptotic behavior in geminate diffusion-influenced reaction

Kyril M. Solntsev; Noam Agmon

doi:10.1016/S0009-2614(00)00190-1

Dual asymptotic behavior in geminate diffusion-influenced reaction

Kyril M. Solntsev
, Noam Agmon

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The kinetics of excited-state proton transfer to solvent from the strong photoacid 5-cyano-2-naphthol exhibits two different power-law asymptotic tails for acid and base, arising from competition between reversible and irreversible geminate reprotonation. We show that the data are in quantitative agreement with a recently developed theory for this diffusion-influenced reaction.

Original language	English
Pages (from-to)	262-268
Number of pages	7
Journal	Chemical Physics Letters
Volume	320
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(00)00190-1
State	Published - 7 Apr 2000

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title = "Dual asymptotic behavior in geminate diffusion-influenced reaction",

abstract = "The kinetics of excited-state proton transfer to solvent from the strong photoacid 5-cyano-2-naphthol exhibits two different power-law asymptotic tails for acid and base, arising from competition between reversible and irreversible geminate reprotonation. We show that the data are in quantitative agreement with a recently developed theory for this diffusion-influenced reaction.",

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AU - Agmon, Noam

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N2 - The kinetics of excited-state proton transfer to solvent from the strong photoacid 5-cyano-2-naphthol exhibits two different power-law asymptotic tails for acid and base, arising from competition between reversible and irreversible geminate reprotonation. We show that the data are in quantitative agreement with a recently developed theory for this diffusion-influenced reaction.

AB - The kinetics of excited-state proton transfer to solvent from the strong photoacid 5-cyano-2-naphthol exhibits two different power-law asymptotic tails for acid and base, arising from competition between reversible and irreversible geminate reprotonation. We show that the data are in quantitative agreement with a recently developed theory for this diffusion-influenced reaction.

UR - https://www.scopus.com/pages/publications/0001588612

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

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Dual asymptotic behavior in geminate diffusion-influenced reaction

Abstract

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