Abstract
The extraction of the two competing reactions from the same catalyst - a composite catalytic-complex@catalytic-metal - is reported. A Wilkinson rhodium based catalyst entrapped within metallic palladium catalyst is shown to perform both hydroformylation and hydrogenation with a ratio that depends on H2 and CO pressures. Here we demonstrate this special reactivity in a one-pot, four step sequence, which include hydroformylations of phenyl acetylenes, reduction of nitrobenzene to aniline, carbonyl-amine condensations forming imines; and imine reductions.
Original language | English |
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Pages (from-to) | 2033-2037 |
Number of pages | 5 |
Journal | ChemCatChem |
Volume | 7 |
Issue number | 14 |
DOIs | |
State | Published - 13 Jul 2015 |
Bibliographical note
Publisher Copyright:© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
- heterogeneous catalysis
- mesoporous materials
- multiple catalysis
- organic-inorganic hybrid composites
- supported catalysts