Dye-sensitized polyoxometalate for visible-light-driven photoelectrochemical cells

Junkuo Gao; Jianwei Miao; Yongxin Li; Rakesh Ganguly; Yang Zhao; Ovadia Lev; Bin Liu; Qichun Zhang

doi:10.1039/c5dt01769f

Dye-sensitized polyoxometalate for visible-light-driven photoelectrochemical cells

Junkuo Gao, Jianwei Miao, Yongxin Li, Rakesh Ganguly, Yang Zhao, Ovadia Lev, Bin Liu^*, Qichun Zhang

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A simple and facile one-step method for the synthesis of an organic dye-functionalized polyoxometalate (POM) hybrid with visible-light photo-response was reported. The POM hybrid was fully characterized via single crystal XRD, powder XRD, FTIR and elemental analysis. The reaction of the organic dye with inorganic salts gave the dye-functionalized POM (MoBB3), in which the POM cluster was formed in situ. The electronic absorption peak of this hybrid was successfully extended beyond 680 nm. Photoelectrochemical measurement indicated that MoBB3 was photoresponsive under visible-light illumination, suggesting that it is an n-type (electron conductive) semiconducting material. This result might offer a method for the design of novel organic dye-functionalized POMs for photoelectric applications.

Original language	English
Pages (from-to)	14354-14358
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	32
DOIs	https://doi.org/10.1039/c5dt01769f
State	Published - 28 Aug 2015

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© The Royal Society of Chemistry 2015.

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abstract = "A simple and facile one-step method for the synthesis of an organic dye-functionalized polyoxometalate (POM) hybrid with visible-light photo-response was reported. The POM hybrid was fully characterized via single crystal XRD, powder XRD, FTIR and elemental analysis. The reaction of the organic dye with inorganic salts gave the dye-functionalized POM (MoBB3), in which the POM cluster was formed in situ. The electronic absorption peak of this hybrid was successfully extended beyond 680 nm. Photoelectrochemical measurement indicated that MoBB3 was photoresponsive under visible-light illumination, suggesting that it is an n-type (electron conductive) semiconducting material. This result might offer a method for the design of novel organic dye-functionalized POMs for photoelectric applications.",

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AU - Gao, Junkuo

AU - Miao, Jianwei

AU - Li, Yongxin

AU - Ganguly, Rakesh

AU - Zhao, Yang

AU - Lev, Ovadia

AU - Liu, Bin

AU - Zhang, Qichun

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Dye-sensitized polyoxometalate for visible-light-driven photoelectrochemical cells

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