Dynamics of chemical reactions induced by cluster impact

T. Raz; R. D. Levine

doi:10.1007/978-3-642-80299-7_11

Dynamics of chemical reactions induced by cluster impact

T. Raz^*
, R. D. Levine

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A new area in dynamics, characterized by collision times shorter than hitherto studied, is discussed with special reference to four-center reactions. Under the unusual combination of conditions made possible within an impact heated cluster, the nominally four-center reactions can be made to proceed (on the computer) via the four-center mechanism as suggested by Bodenstein. It is even possible to achieve multi-center (> 4) reactions. The unique features of the new dynamical regime are discussed and illustrated by a variety of high-barrier processes, including the four center H₂ + I₂ → 2HI and N₂ + O₂ → 2NO reactions and a multi-center "burning of air" process.

Original language	English
Pages (from-to)	155-164
Number of pages	10
Journal	Springer Series in Chemical Physics
Volume	61
DOIs	https://doi.org/10.1007/978-3-642-80299-7_11
State	Published - 1996

Access to Document

10.1007/978-3-642-80299-7_11

Cite this

@article{6179b51917d3474a89c29a49f97a15c4,

title = "Dynamics of chemical reactions induced by cluster impact",

abstract = "A new area in dynamics, characterized by collision times shorter than hitherto studied, is discussed with special reference to four-center reactions. Under the unusual combination of conditions made possible within an impact heated cluster, the nominally four-center reactions can be made to proceed (on the computer) via the four-center mechanism as suggested by Bodenstein. It is even possible to achieve multi-center (> 4) reactions. The unique features of the new dynamical regime are discussed and illustrated by a variety of high-barrier processes, including the four center H2 + I2 → 2HI and N2 + O2 → 2NO reactions and a multi-center {"}burning of air{"} process.",

author = "T. Raz and Levine, \{R. D.\}",

year = "1996",

doi = "10.1007/978-3-642-80299-7\_11",

language = "אנגלית",

volume = "61",

pages = "155--164",

journal = "Springer Series in Chemical Physics",

issn = "0172-6218",

publisher = "Springer New York",

}

TY - JOUR

T1 - Dynamics of chemical reactions induced by cluster impact

AU - Raz, T.

AU - Levine, R. D.

PY - 1996

Y1 - 1996

N2 - A new area in dynamics, characterized by collision times shorter than hitherto studied, is discussed with special reference to four-center reactions. Under the unusual combination of conditions made possible within an impact heated cluster, the nominally four-center reactions can be made to proceed (on the computer) via the four-center mechanism as suggested by Bodenstein. It is even possible to achieve multi-center (> 4) reactions. The unique features of the new dynamical regime are discussed and illustrated by a variety of high-barrier processes, including the four center H2 + I2 → 2HI and N2 + O2 → 2NO reactions and a multi-center "burning of air" process.

AB - A new area in dynamics, characterized by collision times shorter than hitherto studied, is discussed with special reference to four-center reactions. Under the unusual combination of conditions made possible within an impact heated cluster, the nominally four-center reactions can be made to proceed (on the computer) via the four-center mechanism as suggested by Bodenstein. It is even possible to achieve multi-center (> 4) reactions. The unique features of the new dynamical regime are discussed and illustrated by a variety of high-barrier processes, including the four center H2 + I2 → 2HI and N2 + O2 → 2NO reactions and a multi-center "burning of air" process.

UR - https://www.scopus.com/pages/publications/26944472091

U2 - 10.1007/978-3-642-80299-7_11

DO - 10.1007/978-3-642-80299-7_11

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:26944472091

SN - 0172-6218

VL - 61

SP - 155

EP - 164

JO - Springer Series in Chemical Physics

JF - Springer Series in Chemical Physics

ER -

Dynamics of chemical reactions induced by cluster impact

Abstract

Access to Document

Other files and links

Fingerprint

Cite this