Effect of Oxalic Acid Treatment on Conductive Coatings Formed by Ni@Ag Core–Shell Nanoparticles

Anna Pajor-świerzy, Radosław Pawłowski, Piotr Sobik, Alexander Kamyshny, Krzysztof Szczepanowicz

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Low-cost metallic nanoink based on nickel–silver core–shell nanoparticles (Ni@Ag NPs) was used for the formation of conductive metallic coatings with low sintering temperature, which can be successfully applied for replacement of currently used silver-based nanoinks in printed electronics. The effect of oxalic acid (OA) on the sintering temperature and conductivity of coatings formed by Ni@Ag NPs was evaluated. It was found that the addition of OA to the ink formulation and postprinting treatment of deposited films with this acid provided a noticeable decrease in the sintering temperature required for obtaining conductive patterns that is especially important for utilizing the polymeric substrates. The obtained resistivity of metallic coatings after sintering at temperature as low as 100C was found to be 30 µΩ·cm, only ~4 times higher compared to the resistivity of bulk Ni that is promising for future application of such materials for fabrication of low-cost flexible printed patterns.

Original languageAmerican English
Article number305
JournalMaterials
Volume15
Issue number1
DOIs
StatePublished - 1 Jan 2022

Bibliographical note

Publisher Copyright:
© 2022 by the authors. Licensee MDPI, Basel, Switzerland.

Keywords

  • Conductive coatings
  • Conductivity
  • Nickel–silver core–shell nanoparticles
  • Oxalic acid
  • Sintering

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