Electrochemical decomposition of biformylperoxide. A quantum mechanical calculation

Michael Albeck; Sason Shaik

doi:10.1039/F19787401496

Electrochemical decomposition of biformylperoxide. A quantum mechanical calculation

Michael Albeck^*
, Sason Shaik

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Quantum mechanical calculations were performed on the primary products of electrodic redox reactions of biformylperoxide. The calculations predicted that CO₂, O₂, H₂, (chemical equation presented), H₂CO and HCOOH should be the final products of the reaction. Experiments on benzoylperoxide showed the presence of O₂, (chemical equation presented) and (chemical equation presented) beside CO₂, φφ and (chemical equation presented) which are also the thermal decomposition products of benzoylperoxide.

Original language	English
Pages (from-to)	1496-1499
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	74
DOIs	https://doi.org/10.1039/F19787401496
State	Published - 1978
Externally published	Yes

Access to Document

10.1039/F19787401496

Cite this

@article{36a9dd8fd3c044b6bb671293d7353f8a,

title = "Electrochemical decomposition of biformylperoxide. A quantum mechanical calculation",

abstract = "Quantum mechanical calculations were performed on the primary products of electrodic redox reactions of biformylperoxide. The calculations predicted that CO2, O2, H2, (chemical equation presented), H2CO and HCOOH should be the final products of the reaction. Experiments on benzoylperoxide showed the presence of O2, (chemical equation presented) and (chemical equation presented) beside CO2, φφ and (chemical equation presented) which are also the thermal decomposition products of benzoylperoxide.",

author = "Michael Albeck and Sason Shaik",

year = "1978",

doi = "10.1039/F19787401496",

language = "אנגלית",

volume = "74",

pages = "1496--1499",

journal = "Physical Chemistry Chemical Physics",

issn = "0300-9599",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Electrochemical decomposition of biformylperoxide. A quantum mechanical calculation

AU - Albeck, Michael

AU - Shaik, Sason

PY - 1978

Y1 - 1978

N2 - Quantum mechanical calculations were performed on the primary products of electrodic redox reactions of biformylperoxide. The calculations predicted that CO2, O2, H2, (chemical equation presented), H2CO and HCOOH should be the final products of the reaction. Experiments on benzoylperoxide showed the presence of O2, (chemical equation presented) and (chemical equation presented) beside CO2, φφ and (chemical equation presented) which are also the thermal decomposition products of benzoylperoxide.

AB - Quantum mechanical calculations were performed on the primary products of electrodic redox reactions of biformylperoxide. The calculations predicted that CO2, O2, H2, (chemical equation presented), H2CO and HCOOH should be the final products of the reaction. Experiments on benzoylperoxide showed the presence of O2, (chemical equation presented) and (chemical equation presented) beside CO2, φφ and (chemical equation presented) which are also the thermal decomposition products of benzoylperoxide.

UR - https://www.scopus.com/pages/publications/37049095669

U2 - 10.1039/F19787401496

DO - 10.1039/F19787401496

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:37049095669

SN - 0300-9599

VL - 74

SP - 1496

EP - 1499

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

ER -

Electrochemical decomposition of biformylperoxide. A quantum mechanical calculation

Abstract

Access to Document

Other files and links

Fingerprint

Cite this