TY - JOUR
T1 - Electrochemical polymerization of 10-undecenoic acid
AU - Gozlan, A.
AU - Zilkha, A.
PY - 1989
Y1 - 1989
N2 - The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (α, ω-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.
AB - The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (α, ω-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.
UR - http://www.scopus.com/inward/record.url?scp=0024940053&partnerID=8YFLogxK
U2 - 10.1016/0014-3057(89)90061-X
DO - 10.1016/0014-3057(89)90061-X
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AN - SCOPUS:0024940053
SN - 0014-3057
VL - 25
SP - 121
EP - 124
JO - European Polymer Journal
JF - European Polymer Journal
IS - 2
ER -