Electrochemical polymerization of 10-undecenoic acid

A. Gozlan; A. Zilkha

doi:10.1016/0014-3057(89)90061-X

Electrochemical polymerization of 10-undecenoic acid

A. Gozlan^*
, A. Zilkha

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (α, ω-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.

Original language	English
Pages (from-to)	121-124
Number of pages	4
Journal	European Polymer Journal
Volume	25
Issue number	2
DOIs	https://doi.org/10.1016/0014-3057(89)90061-X
State	Published - 1989

Access to Document

10.1016/0014-3057(89)90061-X

Cite this

@article{2a4102a4be414df0a0aac8992710af77,

title = "Electrochemical polymerization of 10-undecenoic acid",

abstract = "The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (α, ω-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25\% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.",

author = "A. Gozlan and A. Zilkha",

year = "1989",

doi = "10.1016/0014-3057(89)90061-X",

language = "אנגלית",

volume = "25",

pages = "121--124",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd.",

number = "2",

}

TY - JOUR

T1 - Electrochemical polymerization of 10-undecenoic acid

AU - Gozlan, A.

AU - Zilkha, A.

PY - 1989

Y1 - 1989

N2 - The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (α, ω-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.

AB - The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (α, ω-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.

UR - https://www.scopus.com/pages/publications/0024940053

U2 - 10.1016/0014-3057(89)90061-X

DO - 10.1016/0014-3057(89)90061-X

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0024940053

SN - 0014-3057

VL - 25

SP - 121

EP - 124

JO - European Polymer Journal

JF - European Polymer Journal

IS - 2

ER -

Electrochemical polymerization of 10-undecenoic acid

Abstract

Access to Document

Other files and links

Fingerprint

Cite this