TY - JOUR
T1 - Electrochemical polymerization of dicarboxylic acids-I. Polymerization of adipic acid
AU - Gozlan, A.
AU - Agam, G.
AU - Vardi, S.
AU - Zilkha, A.
PY - 1984
Y1 - 1984
N2 - The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in various solvent systems. High melting insoluble polymers were obtained; they contained, besides the hydrocarbon chains obtained from the free radical Kolbe mechanism {A figure is presented} ester groups obtained through the cationic mechanism {A figure is presented} Polymer yield, as well as ester group content, increased on passing from methanol to methanol-pyridine (1:4). The structure of the polymers is discussed.
AB - The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in various solvent systems. High melting insoluble polymers were obtained; they contained, besides the hydrocarbon chains obtained from the free radical Kolbe mechanism {A figure is presented} ester groups obtained through the cationic mechanism {A figure is presented} Polymer yield, as well as ester group content, increased on passing from methanol to methanol-pyridine (1:4). The structure of the polymers is discussed.
UR - http://www.scopus.com/inward/record.url?scp=48749136989&partnerID=8YFLogxK
U2 - 10.1016/0014-3057(84)90110-1
DO - 10.1016/0014-3057(84)90110-1
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AN - SCOPUS:48749136989
SN - 0014-3057
VL - 20
SP - 759
EP - 763
JO - European Polymer Journal
JF - European Polymer Journal
IS - 8
ER -