TY - JOUR
T1 - Electrochemical polymerization of dicarboxylic acids-III. Quantitative results in the electrolysis of adipic acid
AU - Gozlan, A.
AU - Zilkha, A.
PY - 1987
Y1 - 1987
N2 - The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.
AB - The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.
UR - http://www.scopus.com/inward/record.url?scp=0004509321&partnerID=8YFLogxK
U2 - 10.1016/0014-3057(87)90024-3
DO - 10.1016/0014-3057(87)90024-3
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AN - SCOPUS:0004509321
SN - 0014-3057
VL - 23
SP - 133
EP - 141
JO - European Polymer Journal
JF - European Polymer Journal
IS - 2
ER -