Electrochemical polymerization of dicarboxylic acids-III. Quantitative results in the electrolysis of adipic acid

A. Gozlan; A. Zilkha

doi:10.1016/0014-3057(87)90024-3

Electrochemical polymerization of dicarboxylic acids-III. Quantitative results in the electrolysis of adipic acid

A. Gozlan^*
, A. Zilkha

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C₄ and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.

Original language	English
Pages (from-to)	133-141
Number of pages	9
Journal	European Polymer Journal
Volume	23
Issue number	2
DOIs	https://doi.org/10.1016/0014-3057(87)90024-3
State	Published - 1987

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title = "Electrochemical polymerization of dicarboxylic acids-III. Quantitative results in the electrolysis of adipic acid",

abstract = "The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.",

author = "A. Gozlan and A. Zilkha",

year = "1987",

doi = "10.1016/0014-3057(87)90024-3",

language = "אנגלית",

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journal = "European Polymer Journal",

issn = "0014-3057",

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AU - Gozlan, A.

AU - Zilkha, A.

PY - 1987

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N2 - The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.

AB - The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.

UR - https://www.scopus.com/pages/publications/0004509321

U2 - 10.1016/0014-3057(87)90024-3

DO - 10.1016/0014-3057(87)90024-3

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AN - SCOPUS:0004509321

SN - 0014-3057

VL - 23

SP - 133

EP - 141

JO - European Polymer Journal

JF - European Polymer Journal

IS - 2

ER -

Electrochemical polymerization of dicarboxylic acids-III. Quantitative results in the electrolysis of adipic acid

Abstract

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