Electrochemically Induced Sol-Gel Deposition of Zirconia Thin Films

Ronen Shacham, Daniel Mandler*, David Avnir

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

65 Scopus citations


A novel electrochemical method for deposition of ZrO2 thin films is described. The films, 50-600 nm thick, were obtained by applying moderate positive or negative potentials (+ 2.5 V to -1.5 V versus SHE) on conducting surfaces immersed in a 2-propanol solution of zirconium tetra-n-propoxide [Zr(OPr)4] in the presence of minute quantities of water (water/monomer molar ratios in the range of 10-5 to 10 -1), which was the limiting reagent. Oxidative electrochemical formation of solvated H+ and reductive formation of OH- catalyze the hydrolysis and condensation of the metal alkoxide precursor. The magnitude of the applied potential and its duration provide a convenient way of controlling the film thickness. The films consist of an amorphous phase, as revealed by XRD measurements. The effects of different parameters, such as the applied potential and its duration, the amount of added water and the current-time characteristics, were studied. A mechanism for the electrodeposition of the zirconia films which is in accordance with our findings is proposed.

Original languageAmerican English
Pages (from-to)1936-1943
Number of pages8
JournalChemistry - A European Journal
Issue number8
StatePublished - 19 Apr 2004


  • Electrochemistry
  • Solgel processes
  • Thin films
  • Zirconia


Dive into the research topics of 'Electrochemically Induced Sol-Gel Deposition of Zirconia Thin Films'. Together they form a unique fingerprint.

Cite this