Electron exchange between aromatic nitro compounds and their anion radicals

N. M. Katkova; I. I. Bil'kis; S. M. Shein

doi:10.1007/BF00922373

Electron exchange between aromatic nitro compounds and their anion radicals

N. M. Katkova^*, I. I. Bil'kis, S. M. Shein

^*Corresponding author for this work

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Abstract

1. The rate of the electron exchange between o-nitrochlorobenzene and its anion radical is significantly smaller than that expected from the correlation between logk_exc and a_N obtained for the meta- and para-substituted nitrobenzene. 2. The study of the spin-spin exchange in the anion radicals showed that the degree of overlap between the orbitals has no effect on electron exchange in the series of substituted nitrobenzenes.

Original language	English
Pages (from-to)	751-754
Number of pages	4
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	25
Issue number	4
DOIs	https://doi.org/10.1007/BF00922373
State	Published - Apr 1976
Externally published	Yes

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title = "Electron exchange between aromatic nitro compounds and their anion radicals",

abstract = "1. The rate of the electron exchange between o-nitrochlorobenzene and its anion radical is significantly smaller than that expected from the correlation between logkexc and aN obtained for the meta- and para-substituted nitrobenzene. 2. The study of the spin-spin exchange in the anion radicals showed that the degree of overlap between the orbitals has no effect on electron exchange in the series of substituted nitrobenzenes.",

author = "Katkova, {N. M.} and Bil'kis, {I. I.} and Shein, {S. M.}",

year = "1976",

month = apr,

doi = "10.1007/BF00922373",

language = "אנגלית",

volume = "25",

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T1 - Electron exchange between aromatic nitro compounds and their anion radicals

AU - Katkova, N. M.

AU - Bil'kis, I. I.

AU - Shein, S. M.

PY - 1976/4

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N2 - 1. The rate of the electron exchange between o-nitrochlorobenzene and its anion radical is significantly smaller than that expected from the correlation between logkexc and aN obtained for the meta- and para-substituted nitrobenzene. 2. The study of the spin-spin exchange in the anion radicals showed that the degree of overlap between the orbitals has no effect on electron exchange in the series of substituted nitrobenzenes.

AB - 1. The rate of the electron exchange between o-nitrochlorobenzene and its anion radical is significantly smaller than that expected from the correlation between logkexc and aN obtained for the meta- and para-substituted nitrobenzene. 2. The study of the spin-spin exchange in the anion radicals showed that the degree of overlap between the orbitals has no effect on electron exchange in the series of substituted nitrobenzenes.

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SN - 0568-5230

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 4

ER -

Electron exchange between aromatic nitro compounds and their anion radicals

Abstract

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