Electron transfer mechanisms: A mechanistic changeover induced by an intramolecular spacer in a model reaction of the NH3/C 2H4·+ pair

A. Chandrasekhar Reddy; G. Narahari Sastry; Sason Shaik

Electron transfer mechanisms: A mechanistic changeover induced by an intramolecular spacer in a model reaction of the NH₃/C ₂H₄^·+ pair

A. Chandrasekhar Reddy
, G. Narahari Sastry
, Sason Shaik^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single -CH ₂-spacer. An isotope effect probe is suggested to detect this mechanistic changeover.

Original language	English
Pages (from-to)	1717-1719
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	9
State	Published - 1995

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title = "Electron transfer mechanisms: A mechanistic changeover induced by an intramolecular spacer in a model reaction of the NH3/C 2H4·+ pair",

abstract = "Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single -CH 2-spacer. An isotope effect probe is suggested to detect this mechanistic changeover.",

author = "\{Chandrasekhar Reddy\}, A. and \{Narahari Sastry\}, G. and Sason Shaik",

year = "1995",

language = "אנגלית",

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journal = "Journal of the Chemical Society, Perkin Transactions 2",

issn = "1472-779X",

publisher = "Chemical Society",

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T1 - Electron transfer mechanisms

T2 - A mechanistic changeover induced by an intramolecular spacer in a model reaction of the NH3/C 2H4·+ pair

AU - Chandrasekhar Reddy, A.

AU - Narahari Sastry, G.

AU - Shaik, Sason

PY - 1995

Y1 - 1995

N2 - Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single -CH 2-spacer. An isotope effect probe is suggested to detect this mechanistic changeover.

AB - Computational evidence is reported for a reversal in the type of an electron transfer (ET) mechanism, induced by an intramolecular linkage of the donor (amine) and acceptor (cation radical) moieties via a single -CH 2-spacer. An isotope effect probe is suggested to detect this mechanistic changeover.

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AN - SCOPUS:37049075019

SN - 1472-779X

SP - 1717

EP - 1719

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

IS - 9

ER -

Electron transfer mechanisms: A mechanistic changeover induced by an intramolecular spacer in a model reaction of the NH₃/C ₂H₄^·+ pair

Abstract

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