Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran

Liza Penn, Alina Shpruhman, Dmitri Gelman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

(Figure Presented) Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(bipheny lphosphine) or a Pd(OAc)2/(R)-(2, 2′-bis(diphenylphosphino)-1,1′-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed.

Original languageAmerican English
Pages (from-to)3875-3879
Number of pages5
JournalJournal of Organic Chemistry
Volume72
Issue number10
DOIs
StatePublished - 11 May 2007

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