Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran

Liza Penn; Alina Shpruhman; Dmitri Gelman

doi:10.1021/jo070170v

Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran

Liza Penn
, Alina Shpruhman
, Dmitri Gelman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

(Figure Presented) Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)₂/(R)-MeO(bipheny lphosphine) or a Pd(OAc)₂/(R)-(2, 2′-bis(diphenylphosphino)-1,1′-binaphthyl) catalyst and a Cu(OAc)₂ reoxidant were employed.

Original language	English
Pages (from-to)	3875-3879
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	72
Issue number	10
DOIs	https://doi.org/10.1021/jo070170v
State	Published - 11 May 2007

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title = "Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran",

abstract = "(Figure Presented) Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(bipheny lphosphine) or a Pd(OAc)2/(R)-(2, 2′-bis(diphenylphosphino)-1,1′-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed.",

author = "Liza Penn and Alina Shpruhman and Dmitri Gelman",

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T1 - Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran

AU - Penn, Liza

AU - Shpruhman, Alina

AU - Gelman, Dmitri

PY - 2007/5/11

Y1 - 2007/5/11

N2 - (Figure Presented) Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(bipheny lphosphine) or a Pd(OAc)2/(R)-(2, 2′-bis(diphenylphosphino)-1,1′-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed.

AB - (Figure Presented) Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(bipheny lphosphine) or a Pd(OAc)2/(R)-(2, 2′-bis(diphenylphosphino)-1,1′-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed.

UR - https://www.scopus.com/pages/publications/34248525511

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DO - 10.1021/jo070170v

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AN - SCOPUS:34248525511

SN - 0022-3263

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SP - 3875

EP - 3879

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 10

ER -

Enantio- and regioselective heck-type reaction of arylboronic acids with 2,3-dihydrofuran

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