Encapsulation of ionic liquid BMIm[PF6] within polyurea microspheres

Ester Weiss, Diana Gertopski, Maneesh Kumar Gupta, Raed Abu-Reziq*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

The encapsulation of 1-butyl-3-methylimidazolium hexafluorophosphate (BMIm[PF6]) in polyurea microspheres is demonstrated. This method is based on the encapsulation of ionic liquid within a polyurea shell by emulsification and interfacial polymerization of amine and isocyanate monomers. Emulsification of BMIm[PF6] was performed in water or oil, enabling formation of two different BMIm[PF6] polyurea microcapsules with different chemical features. While the BMIm[PF6]-in-water emulsion enables the formation of BMIm[PF6] polyurea microcapsules with regular aliphatic diamines, the BMIm[PF6]-in-oil emulsion requires the utilization of a specific diamine functionalized with ionic liquid groups. The microcapsules were characterized by scanning electron microscopy, thermal gravimetric analysis, infrared and solid NMR.

Original languageAmerican English
Article number3560
Pages (from-to)32-38
Number of pages7
JournalReactive and Functional Polymers
Volume96
DOIs
StatePublished - 1 Nov 2015

Bibliographical note

Publisher Copyright:
© 2015 Elsevier B.V.

Keywords

  • Encapsulation
  • Ionic liquid
  • Ionic liquid-in-oil emulsion
  • Ionic liquid-in-water emulsion
  • Polyurea microcapsules

Fingerprint

Dive into the research topics of 'Encapsulation of ionic liquid BMIm[PF6] within polyurea microspheres'. Together they form a unique fingerprint.

Cite this