TY - JOUR
T1 - Energy, entropy and the reaction coordinate
T2 - thermodynamic-like relations in chemical kinetics
AU - Agmon, N.
AU - Levine, R. D.
PY - 1977/12/1
Y1 - 1977/12/1
N2 - A simple thermodynamic-like interpretation of the relation between the kinetic and the thermodynamic parameters of chemical reactions ("linear free energy relations") is discussed and applied. The central concept is the introduction of mixing (or configurational) entropy to account for the activation barrier of chemical reactions.
AB - A simple thermodynamic-like interpretation of the relation between the kinetic and the thermodynamic parameters of chemical reactions ("linear free energy relations") is discussed and applied. The central concept is the introduction of mixing (or configurational) entropy to account for the activation barrier of chemical reactions.
UR - http://www.scopus.com/inward/record.url?scp=0001250519&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(77)80523-X
DO - 10.1016/0009-2614(77)80523-X
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AN - SCOPUS:0001250519
SN - 0009-2614
VL - 52
SP - 197
EP - 201
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 2
ER -