Energy, entropy and the reaction coordinate: thermodynamic-like relations in chemical kinetics

N. Agmon; R. D. Levine

doi:10.1016/0009-2614(77)80523-X

Energy, entropy and the reaction coordinate: thermodynamic-like relations in chemical kinetics

N. Agmon^*
, R. D. Levine

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

211 Scopus citations

Abstract

A simple thermodynamic-like interpretation of the relation between the kinetic and the thermodynamic parameters of chemical reactions ("linear free energy relations") is discussed and applied. The central concept is the introduction of mixing (or configurational) entropy to account for the activation barrier of chemical reactions.

Original language	English
Pages (from-to)	197-201
Number of pages	5
Journal	Chemical Physics Letters
Volume	52
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(77)80523-X
State	Published - 1 Dec 1977

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abstract = "A simple thermodynamic-like interpretation of the relation between the kinetic and the thermodynamic parameters of chemical reactions ({"}linear free energy relations{"}) is discussed and applied. The central concept is the introduction of mixing (or configurational) entropy to account for the activation barrier of chemical reactions.",

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year = "1977",

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AB - A simple thermodynamic-like interpretation of the relation between the kinetic and the thermodynamic parameters of chemical reactions ("linear free energy relations") is discussed and applied. The central concept is the introduction of mixing (or configurational) entropy to account for the activation barrier of chemical reactions.

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Energy, entropy and the reaction coordinate: thermodynamic-like relations in chemical kinetics

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