Energy migration and energy transfer in the system Ce(III)/Tb(III) in β″-alumina crystals

R. Twardowski; M. Eyal; R. Reisfeld; L. A. Momoda; B. Dunn

doi:10.1016/0009-2614(90)85132-V

Energy migration and energy transfer in the system Ce(III)/Tb(III) in β″-alumina crystals

R. Twardowski^*, M. Eyal, R. Reisfeld, L. A. Momoda, B. Dunn

^*Corresponding author for this work

Institute of Chemistry

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Abstract

The parameters of energy migration and energy transfer between Ce(III) and Tb(III) ions in β″-alumina were found by Monte Carlo simulation of experimental decay curves. The polarization measurements reveal significant energy migration in the Ce(III) systems. The value of the critical radius for Ce(III)Ce(III) energy migration is 20.9 ± 1 Å and for energy transfer from Ce(III) to traps is about 24 Å. The critical radius for Ce(III)Tb(III) energy transfer is 3.1 ± 0.1 Å. The results are consistent with two-dimensional space.

Original language	English
Pages (from-to)	211-218
Number of pages	8
Journal	Chemical Physics Letters
Volume	168
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(90)85132-V
State	Published - 27 Apr 1990

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title = "Energy migration and energy transfer in the system Ce(III)/Tb(III) in β″-alumina crystals",

abstract = "The parameters of energy migration and energy transfer between Ce(III) and Tb(III) ions in β″-alumina were found by Monte Carlo simulation of experimental decay curves. The polarization measurements reveal significant energy migration in the Ce(III) systems. The value of the critical radius for Ce(III)Ce(III) energy migration is 20.9 ± 1 {\AA} and for energy transfer from Ce(III) to traps is about 24 {\AA}. The critical radius for Ce(III)Tb(III) energy transfer is 3.1 ± 0.1 {\AA}. The results are consistent with two-dimensional space.",

author = "R. Twardowski and M. Eyal and R. Reisfeld and Momoda, {L. A.} and B. Dunn",

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T1 - Energy migration and energy transfer in the system Ce(III)/Tb(III) in β″-alumina crystals

AU - Twardowski, R.

AU - Eyal, M.

AU - Reisfeld, R.

AU - Momoda, L. A.

AU - Dunn, B.

PY - 1990/4/27

Y1 - 1990/4/27

N2 - The parameters of energy migration and energy transfer between Ce(III) and Tb(III) ions in β″-alumina were found by Monte Carlo simulation of experimental decay curves. The polarization measurements reveal significant energy migration in the Ce(III) systems. The value of the critical radius for Ce(III)Ce(III) energy migration is 20.9 ± 1 Å and for energy transfer from Ce(III) to traps is about 24 Å. The critical radius for Ce(III)Tb(III) energy transfer is 3.1 ± 0.1 Å. The results are consistent with two-dimensional space.

AB - The parameters of energy migration and energy transfer between Ce(III) and Tb(III) ions in β″-alumina were found by Monte Carlo simulation of experimental decay curves. The polarization measurements reveal significant energy migration in the Ce(III) systems. The value of the critical radius for Ce(III)Ce(III) energy migration is 20.9 ± 1 Å and for energy transfer from Ce(III) to traps is about 24 Å. The critical radius for Ce(III)Tb(III) energy transfer is 3.1 ± 0.1 Å. The results are consistent with two-dimensional space.

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Energy migration and energy transfer in the system Ce(III)/Tb(III) in β″-alumina crystals

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