Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents

Glenn Hefter*, Yizhak Marcus, W. Earle Waghorne

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

144 Scopus citations

Abstract

A wide-ranging critically evaluated compilation of the standard molar enthalpies and entropies of transfer of electrolytes from water to mixed aqueous-organic solvents were shown. For this compilation, the reported values were recalculated to obtain a consistent format that enabled comparisons to be made among the data. These whole-salt data were then split into the transfer functions of the individual ions, using an appropriate extrathermodynamic assumption.

Original languageEnglish
Pages (from-to)2773-2836
Number of pages64
JournalChemical Reviews
Volume102
Issue number8
DOIs
StatePublished - Aug 2002

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