Abstract
ESR and susceptibility studies of highly oriented pyrolytic graphite OsF6(C10OsF6) stage-I graphite intercalated compounds are reported. The anisotropy in both ESR and magnetization are interpreted in terms of a quartet ground state of Os+5, 5d3 configuration, in axial local symmetry. The results yield information about charge transfer, anisotropic exchange, spin-orbit coupling, crystal-field splittings and molecular orientation.
Original language | English |
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Pages (from-to) | 3212-3214 |
Number of pages | 3 |
Journal | Physical Review B |
Volume | 31 |
Issue number | 5 |
DOIs | |
State | Published - 1985 |