ESR studies of fluorinated fullerenes: Evidence for the formation of odd C60Fn species

Igal Belaish; Dan Davidov; Heny Selig; John E. Fischer

doi:10.1002/adma.19920040607

ESR studies of fluorinated fullerenes: Evidence for the formation of odd C₆₀F_n species

Igal Belaish^*, Dan Davidov, Heny Selig, John E. Fischer

^*Corresponding author for this work

Racah Institute of Physics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Paramagnetic odd‐fluorinated fullerenes have been observed and characterized by electron spin resonance (ESR), revealing evidence that the fluorination process is inhomogeneous and that these species are not very stable. It is suggested, therefore, that the only method of stabilizing odd fluorinated fullerenes would be to capture the fluorine inside the C₆₀ cage. The relative stability of the various fluorinated fullerenes is discussed.

Original language	English
Pages (from-to)	411-412
Number of pages	2
Journal	Advanced Materials
Volume	4
Issue number	6
DOIs	https://doi.org/10.1002/adma.19920040607
State	Published - Jun 1992

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title = "ESR studies of fluorinated fullerenes: Evidence for the formation of odd C60Fn species",

abstract = "Paramagnetic odd‐fluorinated fullerenes have been observed and characterized by electron spin resonance (ESR), revealing evidence that the fluorination process is inhomogeneous and that these species are not very stable. It is suggested, therefore, that the only method of stabilizing odd fluorinated fullerenes would be to capture the fluorine inside the C60 cage. The relative stability of the various fluorinated fullerenes is discussed.",

author = "Igal Belaish and Dan Davidov and Heny Selig and Fischer, {John E.}",

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AU - Selig, Heny

AU - Fischer, John E.

PY - 1992/6

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N2 - Paramagnetic odd‐fluorinated fullerenes have been observed and characterized by electron spin resonance (ESR), revealing evidence that the fluorination process is inhomogeneous and that these species are not very stable. It is suggested, therefore, that the only method of stabilizing odd fluorinated fullerenes would be to capture the fluorine inside the C60 cage. The relative stability of the various fluorinated fullerenes is discussed.

AB - Paramagnetic odd‐fluorinated fullerenes have been observed and characterized by electron spin resonance (ESR), revealing evidence that the fluorination process is inhomogeneous and that these species are not very stable. It is suggested, therefore, that the only method of stabilizing odd fluorinated fullerenes would be to capture the fluorine inside the C60 cage. The relative stability of the various fluorinated fullerenes is discussed.

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ESR studies of fluorinated fullerenes: Evidence for the formation of odd C₆₀F_n species

Abstract

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