TY - JOUR
T1 - ESR study of graphite-fluorine and graphite-fluoride acceptor intercalation compounds
AU - Davidov, R.
AU - Milo, O.
AU - Palchan, I.
AU - Selig, H.
PY - 1983/12
Y1 - 1983/12
N2 - We report an in situ ESR study of the graphite-fluorine system as well as of the graphite-fluoride acceptor intercalation compounds C:PF5:F2, C:GeF4:F2, C:AsF5, C:SbF5, C:IF5:F2, etc., with emphasis on the ESR line-shape (A/B ratio) and linewidth. The lineshape as a function of exposure time to the fluorine atmosphere can be well described by a modified theory of Dyson. This agreement yields information about the dynamics of the intercalation process. The linewidth increases approximately with the atomic number of the intercalant species, indicating that the conduction carriers are scattered by the intercalants due to the spin-orbit mechanism.
AB - We report an in situ ESR study of the graphite-fluorine system as well as of the graphite-fluoride acceptor intercalation compounds C:PF5:F2, C:GeF4:F2, C:AsF5, C:SbF5, C:IF5:F2, etc., with emphasis on the ESR line-shape (A/B ratio) and linewidth. The lineshape as a function of exposure time to the fluorine atmosphere can be well described by a modified theory of Dyson. This agreement yields information about the dynamics of the intercalation process. The linewidth increases approximately with the atomic number of the intercalant species, indicating that the conduction carriers are scattered by the intercalants due to the spin-orbit mechanism.
UR - http://www.scopus.com/inward/record.url?scp=0020997233&partnerID=8YFLogxK
U2 - 10.1016/0379-6779(83)90014-0
DO - 10.1016/0379-6779(83)90014-0
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AN - SCOPUS:0020997233
SN - 0379-6779
VL - 8
SP - 83
EP - 87
JO - Synthetic Metals
JF - Synthetic Metals
IS - 1-2
ER -