Estimation of the porosity and refractive index of sol-gel silica films using high resolution electron microscopy

Yair Tamar*, Masada Tzabari, Carynelisa Haspel, Yoel Sasson

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The relationship between the refractive index and the porosity of silica based anti-reflective coatings (ARCs) has been studied. The coatings were prepared with the traditional Stöber method. The refractive index was evaluated by fitting vis-NIR transmittance spectra to Fresnels coefficient of reflection using the transfer matrix method. The porosity was assessed by a novel method based on image processing of high resolution scanning electron microscope (SEM) images. Results were compared to the commonly used Yoldas and Maxwell-Garnett mixing rules. Our results showed better agreement with the Yoldas mixing rule than with the Maxwell-Garnett mixing rule, which was explained as being due to the presence of elongated crack shaped pores in the ARCs rather than randomly dispersed spherical shaped pores, as was evident in the SEM images. Furthermore, we found that despite the presence of the elongated cracks, the coating appears to behave towards light like a homogenous medium. This somewhat surprising result calls for further research. Lastly, we have shown that it is reasonable to assume that the ARC is vertically homogeneous in terms of its porosity and effective refractive index.

Original languageAmerican English
Pages (from-to)246-256
Number of pages11
JournalSolar Energy Materials and Solar Cells
Volume130
DOIs
StatePublished - Nov 2014

Bibliographical note

Funding Information:
The authors would like to thank the Ring Family Foundation for their generous support of this research. Additionally, the authors would like to thank Julia Aronson for her valuable advice regarding image processing and Matan Khahanov for his valuable advise about optics related issues. CH thanks Ari Sihvola for helpful discussions regarding mixing rules in general.

Keywords

  • Anti-reflective
  • Mixing rule
  • Porosity
  • Silica
  • Sol-gel
  • Stober

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