Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

J. Segall; Y. Wen; R. Singer; C. Wittig; A. García-Vela; R. B. Gerber

doi:10.1016/0009-2614(93)89037-I

Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

J. Segall^*, Y. Wen, R. Singer, C. Wittig, A. García-Vela, R. B. Gerber

^*Corresponding author for this work

Institute of Chemistry

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Abstract

Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

Original language	English
Pages (from-to)	504-509
Number of pages	6
Journal	Chemical Physics Letters
Volume	207
Issue number	4-6
DOIs	https://doi.org/10.1016/0009-2614(93)89037-I
State	Published - 28 May 1993

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abstract = "Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.",

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AU - Segall, J.

AU - Wen, Y.

AU - Singer, R.

AU - Wittig, C.

AU - García-Vela, A.

AU - Gerber, R. B.

PY - 1993/5/28

Y1 - 1993/5/28

N2 - Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

AB - Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

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Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

Abstract

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