Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

J. Segall; Y. Wen; R. Singer; C. Wittig; A. García-Vela; R. B. Gerber

doi:10.1016/0009-2614(93)89037-I

Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

J. Segall^*, Y. Wen, R. Singer, C. Wittig, A. García-Vela, R. B. Gerber

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

Original language	English
Pages (from-to)	504-509
Number of pages	6
Journal	Chemical Physics Letters
Volume	207
Issue number	4-6
DOIs	https://doi.org/10.1016/0009-2614(93)89037-I
State	Published - 28 May 1993

Access to Document

10.1016/0009-2614(93)89037-I

Cite this

@article{a04a01229bca4850b3e184aa98e65d4c,

title = "Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results",

abstract = "Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.",

author = "J. Segall and Y. Wen and R. Singer and C. Wittig and A. Garc{\'i}a-Vela and Gerber, \{R. B.\}",

year = "1993",

month = may,

day = "28",

doi = "10.1016/0009-2614(93)89037-I",

language = "אנגלית",

volume = "207",

pages = "504--509",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "4-6",

}

TY - JOUR

T1 - Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

AU - Segall, J.

AU - Wen, Y.

AU - Singer, R.

AU - Wittig, C.

AU - García-Vela, A.

AU - Gerber, R. B.

PY - 1993/5/28

Y1 - 1993/5/28

N2 - Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

AB - Evidence for a cage effect in the 193 nm photodissociation of HBr in the ArHBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

UR - https://www.scopus.com/pages/publications/0001141863

U2 - 10.1016/0009-2614(93)89037-I

DO - 10.1016/0009-2614(93)89037-I

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0001141863

SN - 0009-2614

VL - 207

SP - 504

EP - 509

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Evidence for a cage effect in the UV photolysis of HBr in ArHBr. Theoretical and experimental results

Abstract

Access to Document

Other files and links

Fingerprint

Cite this