Evidence for adduct formation between ONOO- and CO2 from high-pressure pulse radiolysis

Sara Goldstein; Dan Meyerstein; Rudi Van Eldik; Gidon Czapski

doi:10.1021/jp002093c

Evidence for adduct formation between ONOO^- and CO₂ from high-pressure pulse radiolysis

Sara Goldstein
, Dan Meyerstein
, Rudi Van Eldik
, Gidon Czapski

School of Nursing

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The activation volume for the reaction of CO₂ with ONOO^- has been determined to be -22 cm³ mol^-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO^- and CO₂.

Original language	English
Pages (from-to)	9712-9714
Number of pages	3
Journal	Journal of Physical Chemistry A
Volume	104
Issue number	43
DOIs	https://doi.org/10.1021/jp002093c
State	Published - 2 Nov 2000

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@article{7c868eff4bb24fca83ab14773b47a26d,

title = "Evidence for adduct formation between ONOO- and CO2 from high-pressure pulse radiolysis",

abstract = "The activation volume for the reaction of CO2 with ONOO- has been determined to be -22 cm3 mol-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO- and CO2.",

author = "Sara Goldstein and Dan Meyerstein and \{Van Eldik\}, Rudi and Gidon Czapski",

year = "2000",

month = nov,

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doi = "10.1021/jp002093c",

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T1 - Evidence for adduct formation between ONOO- and CO2 from high-pressure pulse radiolysis

AU - Goldstein, Sara

AU - Meyerstein, Dan

AU - Van Eldik, Rudi

AU - Czapski, Gidon

PY - 2000/11/2

Y1 - 2000/11/2

N2 - The activation volume for the reaction of CO2 with ONOO- has been determined to be -22 cm3 mol-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO- and CO2.

AB - The activation volume for the reaction of CO2 with ONOO- has been determined to be -22 cm3 mol-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO- and CO2.

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U2 - 10.1021/jp002093c

DO - 10.1021/jp002093c

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AN - SCOPUS:0034322716

SN - 1089-5639

VL - 104

SP - 9712

EP - 9714

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 43

ER -

Evidence for adduct formation between ONOO^- and CO₂ from high-pressure pulse radiolysis

Abstract

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