Exact solution for the geminate ABCD reaction

Alexander V. Popov; Noam Agmon

doi:10.1063/1.1501127

Exact solution for the geminate ABCD reaction

Alexander V. Popov, Noam Agmon^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

An ABCD reaction representing a general reversible transfer reaction in solution, such as energy transfer (A+B*↔A*+B)², or atom transfer (A+BC↔AB+C) is introduced. It is also a simplified version of a catalytic or enzymatic reaction of the type E+S↔E+P. Here, the enzyme E is unchanged while a substrate (S) is converted into a product (P). The reversible Michaelis-Menten scheme, E+S↔ES↔E+P, reduces to it for small ligand concentrations.

Original language	English
Pages (from-to)	5770-5779
Number of pages	10
Journal	Journal of Chemical Physics
Volume	117
Issue number	12
DOIs	https://doi.org/10.1063/1.1501127
State	Published - 22 Sep 2002

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Exact solution for the geminate ABCD reaction

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