Excimer emission spectrum in noble gas systems

V. Yakhot; R. B. Gerber

doi:10.1016/0301-0104(75)80146-7

Excimer emission spectrum in noble gas systems

V. Yakhot^*
, R. B. Gerber

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A simple expression for the time shape of excimer emission as a function of temperature is obtained for the case of a realistic (exponential) ground state potential. The excimer binding energy and its equilibrium geometry are obtained for the lowest ¹Σ_u states of Ar*₂, Kr*₂, Xe*₂ and for the A¹Σ_u and D¹Σ_u states of Hc*₂, by comparing the theoretical formula with the corresponding experamental results. Agreement with electronic calculations when available of these parameter is very good. The relation between our line-shape expression and those given by other authors is discussed.

Original language	English
Pages (from-to)	366-370
Number of pages	5
Journal	Chemical Physics
Volume	8
Issue number	3
DOIs	https://doi.org/10.1016/0301-0104(75)80146-7
State	Published - May 1975
Externally published	Yes

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abstract = "A simple expression for the time shape of excimer emission as a function of temperature is obtained for the case of a realistic (exponential) ground state potential. The excimer binding energy and its equilibrium geometry are obtained for the lowest 1Σu states of Ar*2, Kr*2, Xe*2 and for the A1Σu and D1Σu states of Hc*2, by comparing the theoretical formula with the corresponding experamental results. Agreement with electronic calculations when available of these parameter is very good. The relation between our line-shape expression and those given by other authors is discussed.",

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AU - Gerber, R. B.

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N2 - A simple expression for the time shape of excimer emission as a function of temperature is obtained for the case of a realistic (exponential) ground state potential. The excimer binding energy and its equilibrium geometry are obtained for the lowest 1Σu states of Ar*2, Kr*2, Xe*2 and for the A1Σu and D1Σu states of Hc*2, by comparing the theoretical formula with the corresponding experamental results. Agreement with electronic calculations when available of these parameter is very good. The relation between our line-shape expression and those given by other authors is discussed.

AB - A simple expression for the time shape of excimer emission as a function of temperature is obtained for the case of a realistic (exponential) ground state potential. The excimer binding energy and its equilibrium geometry are obtained for the lowest 1Σu states of Ar*2, Kr*2, Xe*2 and for the A1Σu and D1Σu states of Hc*2, by comparing the theoretical formula with the corresponding experamental results. Agreement with electronic calculations when available of these parameter is very good. The relation between our line-shape expression and those given by other authors is discussed.

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Excimer emission spectrum in noble gas systems

Abstract

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