Excited-state proton transfer in chiral environments. 1. Chiral solvents

Kyril M. Solntsev; Laren M. Tolbert; Boiko Cohen; Dan Huppert; Yoshihito Hayashi; Yuri Feldman

doi:10.1021/ja026896k

Excited-state proton transfer in chiral environments. 1. Chiral solvents

Kyril M. Solntsev^*
, Laren M. Tolbert
, Boiko Cohen
, Dan Huppert
, Yoshihito Hayashi
, Yuri Feldman

^*Corresponding author for this work

The Institute of Applied Physics

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Excited-state proton transfer from the "super" photoacid 5,8-dicyano-2-naphthol to 2-butanol is faster in the enantiopure solvent than in its racemic form. The difference observed is discussed in terms of long-range order in homo- and heterodimers of 2-butanol.

Original language	English
Pages (from-to)	9046-9047
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	31
DOIs	https://doi.org/10.1021/ja026896k
State	Published - 7 Aug 2002

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10.1021/ja026896k

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abstract = "Excited-state proton transfer from the {"}super{"} photoacid 5,8-dicyano-2-naphthol to 2-butanol is faster in the enantiopure solvent than in its racemic form. The difference observed is discussed in terms of long-range order in homo- and heterodimers of 2-butanol.",

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AU - Solntsev, Kyril M.

AU - Tolbert, Laren M.

AU - Cohen, Boiko

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AU - Hayashi, Yoshihito

AU - Feldman, Yuri

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AB - Excited-state proton transfer from the "super" photoacid 5,8-dicyano-2-naphthol to 2-butanol is faster in the enantiopure solvent than in its racemic form. The difference observed is discussed in terms of long-range order in homo- and heterodimers of 2-butanol.

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Excited-state proton transfer in chiral environments. 1. Chiral solvents

Abstract

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