Experimental determination of the long-time behavior in reversible binary chemical reactions

Dan Huppert; Sinay Y. Goldberg; Asnat Masad; Noam Agmon

doi:10.1103/PhysRevLett.68.3932

Experimental determination of the long-time behavior in reversible binary chemical reactions

Dan Huppert^*
, Sinay Y. Goldberg
, Asnat Masad
, Noam Agmon

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

A new asymptotic behavior of reversible pseudo first-order binary chemical reactions is revealed by time-resolved fluorescence measurements of excited-state proton transfer. The asymptotic behavior is a power-law rather than the exponential decay expected from the chemical rate equations. Unlike the conclusion from mean-field approximations, the power seems to increase with concentration.

Original language	English
Pages (from-to)	3932-3935
Number of pages	4
Journal	Physical Review Letters
Volume	68
Issue number	26
DOIs	https://doi.org/10.1103/PhysRevLett.68.3932
State	Published - 1992

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title = "Experimental determination of the long-time behavior in reversible binary chemical reactions",

abstract = "A new asymptotic behavior of reversible pseudo first-order binary chemical reactions is revealed by time-resolved fluorescence measurements of excited-state proton transfer. The asymptotic behavior is a power-law rather than the exponential decay expected from the chemical rate equations. Unlike the conclusion from mean-field approximations, the power seems to increase with concentration.",

author = "Dan Huppert and Goldberg, \{Sinay Y.\} and Asnat Masad and Noam Agmon",

year = "1992",

doi = "10.1103/PhysRevLett.68.3932",

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AB - A new asymptotic behavior of reversible pseudo first-order binary chemical reactions is revealed by time-resolved fluorescence measurements of excited-state proton transfer. The asymptotic behavior is a power-law rather than the exponential decay expected from the chemical rate equations. Unlike the conclusion from mean-field approximations, the power seems to increase with concentration.

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JO - Physical Review Letters

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Experimental determination of the long-time behavior in reversible binary chemical reactions

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