Experimental study of the D + H2(ν = 1) reaction

V. B. Rozenshtein; Yu M. Gershenzon; A. V. Ivanov; S. I. Kucheryavii

doi:10.1016/0009-2614(84)80054-8

Experimental study of the D + H₂(ν = 1) reaction

V. B. Rozenshtein^*
, Yu M. Gershenzon
, A. V. Ivanov
, S. I. Kucheryavii

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The D + H₂(ν = 1) reaction, D + H₂(ν = 1) → K_a HD(ν = 1) + H, → K_n HD(ν = 0) + H, → K_r D + H₂(ν = 0) has been studied. The measurements were made in a flow-tube apparatus at 300 K. Vibrationally excited H₂ was generated in a furnace and D atoms in a microwave discharge. EPR and thermometric techniques were used for the detection of D and H atoms and H₂(ν = 1). The product branching rate constants (in CM³/Molecule s) were found to be K_a = (10.7 ± 4.1) × 10^-13. K_n = (5.4 ± 2.7) × 10^-13, K_r, < 2.7 × 10^-13.

Original language	English
Pages (from-to)	423-426
Number of pages	4
Journal	Chemical Physics Letters
Volume	105
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(84)80054-8
State	Published - 23 Mar 1984
Externally published	Yes

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title = "Experimental study of the D + H2(ν = 1) reaction",

abstract = "The D + H2(ν = 1) reaction, D + H2(ν = 1) → Ka HD(ν = 1) + H, → Kn HD(ν = 0) + H, → Kr D + H2(ν = 0) has been studied. The measurements were made in a flow-tube apparatus at 300 K. Vibrationally excited H2 was generated in a furnace and D atoms in a microwave discharge. EPR and thermometric techniques were used for the detection of D and H atoms and H2(ν = 1). The product branching rate constants (in CM3/Molecule s) were found to be Ka = (10.7 ± 4.1) × 10-13. Kn = (5.4 ± 2.7) × 10-13, Kr, < 2.7 × 10-13.",

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AU - Rozenshtein, V. B.

AU - Gershenzon, Yu M.

AU - Ivanov, A. V.

AU - Kucheryavii, S. I.

PY - 1984/3/23

Y1 - 1984/3/23

N2 - The D + H2(ν = 1) reaction, D + H2(ν = 1) → Ka HD(ν = 1) + H, → Kn HD(ν = 0) + H, → Kr D + H2(ν = 0) has been studied. The measurements were made in a flow-tube apparatus at 300 K. Vibrationally excited H2 was generated in a furnace and D atoms in a microwave discharge. EPR and thermometric techniques were used for the detection of D and H atoms and H2(ν = 1). The product branching rate constants (in CM3/Molecule s) were found to be Ka = (10.7 ± 4.1) × 10-13. Kn = (5.4 ± 2.7) × 10-13, Kr, < 2.7 × 10-13.

AB - The D + H2(ν = 1) reaction, D + H2(ν = 1) → Ka HD(ν = 1) + H, → Kn HD(ν = 0) + H, → Kr D + H2(ν = 0) has been studied. The measurements were made in a flow-tube apparatus at 300 K. Vibrationally excited H2 was generated in a furnace and D atoms in a microwave discharge. EPR and thermometric techniques were used for the detection of D and H atoms and H2(ν = 1). The product branching rate constants (in CM3/Molecule s) were found to be Ka = (10.7 ± 4.1) × 10-13. Kn = (5.4 ± 2.7) × 10-13, Kr, < 2.7 × 10-13.

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Experimental study of the D + H₂(ν = 1) reaction

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