Exploring the reactivity of C(sp3)-cyclometalated Ir III compounds in hydrogen transfer reactions

Clarite Azerraf, Dmitri Gelman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

63 Scopus citations

Abstract

The manuscript describes the synthesis and full characterization of a new PC(sp3)P-based cyclometalated IrIII complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp3)-metalated compounds.

Original languageAmerican English
Pages (from-to)10364-10368
Number of pages5
JournalChemistry - A European Journal
Volume14
Issue number33
DOIs
StatePublished - 17 Nov 2008

Keywords

  • Cyclometalation
  • Hydrogenation
  • Iridium
  • P ligands
  • Pincer complexes

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