Exploring the reactivity of C(sp3)-cyclometalated Ir III compounds in hydrogen transfer reactions

Clarite Azerraf; Dmitri Gelman

doi:10.1002/chem.200801728

Exploring the reactivity of C(sp³)-cyclometalated Ir ^III compounds in hydrogen transfer reactions

Clarite Azerraf
, Dmitri Gelman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

The manuscript describes the synthesis and full characterization of a new PC(sp³)P-based cyclometalated Ir^III complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp³)-metalated compounds.

Original language	English
Pages (from-to)	10364-10368
Number of pages	5
Journal	Chemistry - A European Journal
Volume	14
Issue number	33
DOIs	https://doi.org/10.1002/chem.200801728
State	Published - 17 Nov 2008

Keywords

Cyclometalation
Hydrogenation
Iridium
P ligands
Pincer complexes

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10.1002/chem.200801728

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abstract = "The manuscript describes the synthesis and full characterization of a new PC(sp3)P-based cyclometalated IrIII complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp3)-metalated compounds.",

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author = "Clarite Azerraf and Dmitri Gelman",

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AU - Azerraf, Clarite

AU - Gelman, Dmitri

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N2 - The manuscript describes the synthesis and full characterization of a new PC(sp3)P-based cyclometalated IrIII complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp3)-metalated compounds.

AB - The manuscript describes the synthesis and full characterization of a new PC(sp3)P-based cyclometalated IrIII complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp3)-metalated compounds.

KW - Cyclometalation

KW - Hydrogenation

KW - Iridium

KW - P ligands

KW - Pincer complexes

UR - https://www.scopus.com/pages/publications/56349085528

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DO - 10.1002/chem.200801728

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AN - SCOPUS:56349085528

SN - 0947-6539

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EP - 10368

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 33

ER -

Exploring the reactivity of C(sp³)-cyclometalated Ir ^III compounds in hydrogen transfer reactions

Abstract

Keywords

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