Abstract
Chloride-bromide halogen exchange was realized when a mixture of an alkyl chloride and an alkyl bromide were reacted over a supported molten alkyl phosphonium catalyst. Conversion was found to be near equilibrium in a tubular flow reactor at 150 °C and 1500 GHSV. The catalyst was prepared by impregnation of alumina or silica support and found to be highly stable for relatively long periods of time. A pathway for the catalytic cycle is proposed.
| Original language | English |
|---|---|
| Pages (from-to) | 2824-2828 |
| Number of pages | 5 |
| Journal | RSC Advances |
| Volume | 8 |
| Issue number | 5 |
| DOIs | |
| State | Published - 2018 |
Bibliographical note
Publisher Copyright:© The Royal Society of Chemistry 2018.
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