First comb-like copolymer of poly(ethyl 2-cyanoacrylate) grafted as a side-chain to dextran

Valery A. Dyatlov; Tatiana S. Seregina; Igor A. Derevnin; Efrem G. Krivoborodov; Anna A. Belyaeva; Anna B. Malashicheva; Alexander V. Dyatlov

doi:10.1016/j.mencom.2024.10.035

First comb-like copolymer of poly(ethyl 2-cyanoacrylate) grafted as a side-chain to dextran

Valery A. Dyatlov^*
, Tatiana S. Seregina
, Igor A. Derevnin
, Efrem G. Krivoborodov
, Anna A. Belyaeva
, Anna B. Malashicheva
, Alexander V. Dyatlov

^*Corresponding author for this work

Department of Biochemistry and Molecular Biology

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The first comb-like cyanoacrylic copolymer was synthesized by anionic polymerization of ethyl 2-cyanoacrylate in an aqueous solution of dextran of M_w = 50 ± 5 kDa. The copolymer was explored by NMR and Fourier IR spectroscopy, as well as by MALDI-TOF mass-spectrometry methods. It contains up to 10 cyanoacrylate units grafted to anhydroglucose cycles of dextran main chain, multi- substituted glycose units were not detected.

Original language	English
Pages (from-to)	881-883
Number of pages	3
Journal	Mendeleev Communications
Volume	34
Issue number	6
DOIs	https://doi.org/10.1016/j.mencom.2024.10.035
State	Published - 1 Nov 2024

Bibliographical note

Publisher Copyright:
© 2024

Keywords

MALDI-TOF mass spectrometry
anionic polymerization
comb-like graft copolymer
dextran
ethyl 2-cyanoacrylate
polysaccharides

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10.1016/j.mencom.2024.10.035

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title = "First comb-like copolymer of poly(ethyl 2-cyanoacrylate) grafted as a side-chain to dextran",

abstract = "The first comb-like cyanoacrylic copolymer was synthesized by anionic polymerization of ethyl 2-cyanoacrylate in an aqueous solution of dextran of Mw = 50 ± 5 kDa. The copolymer was explored by NMR and Fourier IR spectroscopy, as well as by MALDI-TOF mass-spectrometry methods. It contains up to 10 cyanoacrylate units grafted to anhydroglucose cycles of dextran main chain, multi- substituted glycose units were not detected.",

keywords = "MALDI-TOF mass spectrometry, anionic polymerization, comb-like graft copolymer, dextran, ethyl 2-cyanoacrylate, polysaccharides",

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doi = "10.1016/j.mencom.2024.10.035",

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AU - Dyatlov, Valery A.

AU - Seregina, Tatiana S.

AU - Derevnin, Igor A.

AU - Krivoborodov, Efrem G.

AU - Belyaeva, Anna A.

AU - Malashicheva, Anna B.

AU - Dyatlov, Alexander V.

PY - 2024/11/1

Y1 - 2024/11/1

N2 - The first comb-like cyanoacrylic copolymer was synthesized by anionic polymerization of ethyl 2-cyanoacrylate in an aqueous solution of dextran of Mw = 50 ± 5 kDa. The copolymer was explored by NMR and Fourier IR spectroscopy, as well as by MALDI-TOF mass-spectrometry methods. It contains up to 10 cyanoacrylate units grafted to anhydroglucose cycles of dextran main chain, multi- substituted glycose units were not detected.

AB - The first comb-like cyanoacrylic copolymer was synthesized by anionic polymerization of ethyl 2-cyanoacrylate in an aqueous solution of dextran of Mw = 50 ± 5 kDa. The copolymer was explored by NMR and Fourier IR spectroscopy, as well as by MALDI-TOF mass-spectrometry methods. It contains up to 10 cyanoacrylate units grafted to anhydroglucose cycles of dextran main chain, multi- substituted glycose units were not detected.

KW - MALDI-TOF mass spectrometry

KW - anionic polymerization

KW - comb-like graft copolymer

KW - dextran

KW - ethyl 2-cyanoacrylate

KW - polysaccharides

UR - https://www.scopus.com/pages/publications/85210376820

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AN - SCOPUS:85210376820

SN - 0959-9436

VL - 34

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JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 6

ER -

First comb-like copolymer of poly(ethyl 2-cyanoacrylate) grafted as a side-chain to dextran

Abstract

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