Geminate recombination in proton-transfer reactions. IV. Ground-state yields

Noam Agmon

doi:10.1063/1.455149

Geminate recombination in proton-transfer reactions. IV. Ground-state yields

Noam Agmon^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Our calculations of proton-anion distance distribution functions for HPTS dissociation recombination in the excited state are extended to the nanosecond time regime. When these functions are used for averaging the ground-state recombination probability, good agreement with experimental ground-state recombination yields is obtained. The relation with the theory of "delayed" geminate recombination is briefly discussed.

Original language	English
Pages (from-to)	1524-1528
Number of pages	5
Journal	The Journal of Chemical Physics
Volume	89
Issue number	3
DOIs	https://doi.org/10.1063/1.455149
State	Published - 1988

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abstract = "Our calculations of proton-anion distance distribution functions for HPTS dissociation recombination in the excited state are extended to the nanosecond time regime. When these functions are used for averaging the ground-state recombination probability, good agreement with experimental ground-state recombination yields is obtained. The relation with the theory of {"}delayed{"} geminate recombination is briefly discussed.",

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AB - Our calculations of proton-anion distance distribution functions for HPTS dissociation recombination in the excited state are extended to the nanosecond time regime. When these functions are used for averaging the ground-state recombination probability, good agreement with experimental ground-state recombination yields is obtained. The relation with the theory of "delayed" geminate recombination is briefly discussed.

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Geminate recombination in proton-transfer reactions. IV. Ground-state yields

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