Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Rajendra D. Patil; Yoel Sasson

doi:10.1002/ajoc.201500292

Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Rajendra D. Patil^*, Yoel Sasson

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A non-hazordous and mild protocol was developed for an efficient reduction of alkenes to alkanes using "iron-activated water" and catalytic Pd/C (2.5mol%). Water functions as a hydrogen source without any external acid or base and in the absence of another solvent. The Pd/C catalyst was recovered and recycled. In the course of the reaction zero valent iron is oxidized to magnetite.

Original language	English
Pages (from-to)	1258-1261
Number of pages	4
Journal	Asian Journal of Organic Chemistry
Volume	4
Issue number	11
DOIs	https://doi.org/10.1002/ajoc.201500292
State	Published - Nov 2015

Bibliographical note

Publisher Copyright:
& Co. KGaA, Weinheim.

Keywords

Alkenes
Heterogeneous catalysis
Iron
Magnetite
Transfer hydrogenation
Water

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AU - Sasson, Yoel

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PY - 2015/11

Y1 - 2015/11

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KW - Heterogeneous catalysis

KW - Iron

KW - Magnetite

KW - Transfer hydrogenation

KW - Water

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Generation of Hydrogen from Zero-Valent Iron and Water: Catalytic Transfer Hydrogenation of Olefins in Presence of Pd/C

Abstract

Bibliographical note

Keywords

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